|
|
H+ + 3-hydroxybenzoyl-CoA + malonyl-CoA <=> CO2 + 2,3',4,6-tetrahydroxybenzophenone + CoA
|
2.3.1.151
2,3',4,6-tetrahydroxybenzophenone synthase
|
–
|
M
|
|
BRENDA:
BR1627
KEGG:
R04709
MetaCyc:
2.3.1.151-RXN
|
|
|
|
3-hydroxybenzoate + CoA + ATP <=> 3-hydroxybenzoyl-CoA + diphosphate + AMP
|
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.37
3-hydroxybenzoate---CoA ligase
|
–
–
|
M
|
|
BRENDA:
BR49653
KEGG:
R09589
MetaCyc:
RXN-7488
SABIO-RK:
13784
|
|
|
|
benzoyl-CoA + O2 + NADPH + H+ <=> 3-hydroxybenzoyl-CoA + H2O + NADP+
|
1.14.13.58
benzoyl-CoA 3-monooxygenase
|
–
|
BM
|
|
BRENDA:
BR655
KEGG:
R02449
MetaCyc:
1.14.13.58-RXN
|
|
|
|
3-hydroxybenzoyl-CoA + H2O <=> 3-hydroxybenzoate + CoA + H+
|
3.1.2
3.1.2.20
acyl-CoA hydrolase
3.1.2.23
4-hydroxybenzoyl-CoA thioesterase
|
–
–
–
|
B
|
|
BRENDA:
BS403728
MetaCyc:
RXN0-7046
SABIO-RK:
12737
|
|
|
|
3-hydroxybenzoyl-CoA + O2 + reduced_acceptor <=> 2,5-Dihydroxybenzoate + CoA + H+ + acceptor
|
not assigned
|
–
|
M
|
|
MetaCyc:
R246-RXN
|
|
|
|
protocatechuyl-CoA + oxidized_ferredoxin + H2O <=> 3-hydroxybenzoyl-CoA + reduced_ferredoxin
|
1.1.7.1
4-hydroxybenzoyl-CoA reductase
|
–
|
|
|
BRENDA:
BS454472
|
|
|
|
malonyl-CoA + 3-hydroxybenzoyl-CoA <=> 2 CoA + 2-oxabicyclo[4.3.1]deca-1(10),6,8-triene-3,5-dione + CO2
|
2.3.1.208
4-hydroxycoumarin synthase
|
–
|
|
|
BRENDA:
BS419455
|
|
|
|
malonyl-CoA + 3-hydroxybenzoyl-CoA <=> CoA + 2,3'',4,5-tetrahydroxybenzophenone + CO2
|
2.3.1.151
2,3',4,6-tetrahydroxybenzophenone synthase
|
–
|
|
|
BRENDA:
BS409795
|
|
|
|
malonyl-CoA + 3-hydroxybenzoyl-CoA <=> CoA + 3-hydroxycoumarin
|
2.3.1.177
3,5-dihydroxybiphenyl synthase
|
–
|
|
|
BRENDA:
BS380056
|
|